The authors present a comprehensive review of alloys and compounds formed between silver or gold and metals/metalloids from the p-block of the Periodic Table. This review focuses on the phase formation tendencies, preparation methods, and optical properties of these materials. The motivation for studying these alloys and compounds lies in the unique properties of p-block metals, such as their high plasma frequency (ωp). This property makes them interesting for plasmonic applications, as the plasma frequency can be tuned across a wide range in the ultraviolet (UV) spectral region. This review provides valuable insights into the phase behaviour, synthesis, and optical properties of alloys and compounds formed between silver/gold and p-block metals/metalloids. These materials hold great promise for advancing UV plasmonics and finding applications in various fields.
Rosen Todorov, et al. Institute of Optical Materials and Technologies “Acad. J. Malinowski”, Bulgarian Academy of Sciences, Bulgaria.
ACS Omega 2023, 8, 16, 14321–14341